The present work investigates the process of frosting formation on arched copper samples with different surface temperatures, calculated the thickness of the frost layer by using the scale method, and analyzed frost lodging, melting, and other phenomena that appeared during the frost-formation process. The results showed that the frosting process on an arched surface can be divided into ice-film formation, rapid growth of the frost layer, and stable growth of the frost layer. Meanwhile, the phenomena of frost-branch breakage, lodging, and melting were observed. The surface temperature had a large effect on the frost formation and thickness of the frost layer, e.g., the formation time of the ice film on a surface at -5°C was the longest (~135 s), the frost layer formed on a surface at -20°C was the thickest (~660 μm). When microscopic observation of the frosting process was accompanied by calculation of the frost-layer thickness, it could be seen that the appearance of the frost branches was affected by the different thermal conductivities of the frost layers, undulating surface of the ice film, and temperature difference between the layers. The changes in the frost branches and the soft surface of the frost layer also affected the growth of the frost layer. The findings of this study are expected to provide guidelines for optimization of conventional defrosting methods.