Morphological Modification and Analysis of ZnO Nanorods and Their Optical Properties and Polarization

Nandang Mufti; Siti Maryam; Anggun A Fibriyanti; Robi Kurniawan; Abdulloh Fuad; Ahmad Taufiq; Sunaryono

doi:10.1155/2018/6545803

Morphological Modification and Analysis of ZnO Nanorods and Their Optical Properties and Polarization

Scanning. 2018 Nov 5:2018:6545803. doi: 10.1155/2018/6545803. eCollection 2018.

Authors

Nandang Mufti^{1

2}, Siti Maryam¹, Anggun A Fibriyanti¹, Robi Kurniawan¹, Abdulloh Fuad^{1

2}, Ahmad Taufiq^{1

2}, Sunaryono^{1

2}

Affiliations

¹ Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, Jl. Semarang 5, Malang, 65145 East Java, Indonesia.
² Centre of Advanced Materials for Renewable Energy, Universitas Negeri Malang, Jl. Semarang 5, Malang, 65145 East Java, Indonesia.

Abstract

We report on the effect of the morphological modification on optical properties and polarization of ZnO nanorods (NR). Here, the morphology and structure of the ZnO NR were modified by introducing different annealing temperatures. The increase of length and diameter and change in density of the ZnO NR were clearly observed by increasing the annealing temperature. We found that the samples show different oxygen vacancy (V_O) and zinc interstitial (Zn_I) concentrations. We suggest that the different concentrations of V_O and Zn_I are originated from morphological and structural modification. Our results reveal that optical absorption and polarization of ZnO NR could be enhanced by producing a high concentration of V_O and Zn_I. The modification of V_O and Zn_I promotes a decrease in the band gap and coexistence of high optical absorption and polarization in our ZnO NR. Our findings would give a broad insight into the morphological modification and characterization technique on ZnO NR. The high optical and polarization characteristics of ZnO NR are potential for developing the high-performance nanogenerator device for multitype energy harvesting.