A novel configuration of a photothermal gas sensor is demonstrated. Photothermal-induced gas refractive index (RI) modulation is probed by a simple, mode-locked (ML) ring cavity fiber laser, operating in the 1.55 µm wavelength region. The measured gas sample is placed in an open-path section of the ML laser and the RI variations directly translate to its optical path-length change, which is easily detectable as pulse repetition frequency deviations. Wavelength modulation spectroscopy (WMS) technique was used along with a custom-built FM demodulator simplifying the signal retrieval and acquisition. Normalized noise equivalent coefficient calculated for the sensor was 1 x 10-5 cm-1 W Hz-1/2.