Design and Realization of White Quantum Dot Light-Emitting Electrochemical Cell Hybrid Devices

ACS Appl Mater Interfaces. 2018 Dec 12;10(49):42637-42646. doi: 10.1021/acsami.8b15100. Epub 2018 Nov 30.

Abstract

The simple device architecture as well as the solution-based processing makes light-emitting electrochemical cells (LECs) a promising device concept for large-area flexible lighting solutions. The lack of deep-blue emitters, which are, at the same time, efficient, bright, and long-term stable, complementary to the wide variety of yellow-orange-emitting LECs, hampers the creation of white LECs. We present a hybrid device concept for the realization of white light emission by combining blue colloidal quantum dots (QDs) and an Ir-based ionic transition-metal complex (iTMC) LEC in a new type of white QD-LEC hybrid device (QLEC). By careful arrangement of the active layers, we yield light emission from both the blue QDs and the yellow iTMC emitter already at voltages below 3 V. The QLEC devices show homogeneous white light emission with high color rendering index (up to 80), luminance levels above 850 cd m-2, and a maximum external quantum efficiency greater than 0.2%.

Keywords: iTMC; light-emitting electrochemical cells; light-emitting hybrid devices; quantum dots; white light emitters.