Fabrication of a Hydrophilic Line on a Hydrophobic Surface by Laser Ablation Processing

Micromachines (Basel). 2018 Apr 28;9(5):208. doi: 10.3390/mi9050208.

Abstract

A hydrophilic line on a hydrophobic surface was fabricated by using plasma etching and laser ablation processing in this paper. We fabricated the nanospikes on a polyimide surface by using the plasma etching processing. CHF₃ plasma treatment for hydrophobic coating was conducted on these nanospikes. We fabricated the microgrooves on the hydrophobic nanospikes surface using laser ablation processing. The microgroove had hydrophilic characteristics. In order to measure the hydrophilic characteristics of the microgroove, a solution that was dispersed with silver nanoparticles was used. The hydrophilic line on the hydrophobic surface was dipped in the silver nanoparticle solution. The silver nanoparticles were attached on the hydrophilic microgroove and not on the hydrophobic surface. We concluded that the laser heat affected zone should be reduced for reducing the hydrophilic line width. This hydrophilic pattern on the hydrophobic surface can be used for cell growth, protein manipulation, the spotting of biomolecules, micro-fluidics and water collection. This functional surface can especially be used for an electric flexible circuit, which is newly proposed in this paper.

Keywords: hydrophilic; hydrophobic; laser ablation processing; laser micromachining; microgrooves; nanospikes.