Methods for the determination of levoglucosan and other sugar anhydrides as biomass burning tracers in environmental samples - A review

Abstract

Nowadays, there is a great pressure on finding an alternative source of energy. One such source is biomass combustion. Biomass is any organic matter such as wood, crops, seaweed, and animal wastes that during combustion emits energy but also smoke and solid residue. Biomass burning tracers, such as levoglucosan, mannosan and galactosan, are sugar anhydrides produced during burning of biomass that contain cellulose and hemicellulose. Analysis of environmental samples for tracers is the source of information about the type of biofuel burned. In this article, a literature review of the preparation and determination of biomass burning tracers for environmental samples was presented. The review discusses the preparation of different samples (particulate matter, soils, sediments, biological samples), extraction, derivatization, and determination. Amongst determination methods the most popular was gas chromatography with mass spectrometry but other techniques were also used, such as high-performance liquid chromatography with aerosol charge detection, capillary electrophoresis with pulsed amperometric detection, and ion chromatography with pulsed amperometric detection.

Keywords: biomass burning; levoglucosan; sugar anhydrides; tracers.