Towards Green Titration: Batchwise Titration with Reusable Solid Sorbed Indicators

Anal Sci. 2019 Mar 10;35(3):347-350. doi: 10.2116/analsci.18N019. Epub 2018 Oct 19.

Abstract

We propose the creation of reusable indicator-sorbed-solids, using anion-exchange resins or kaolin as supports, with the aim to reduce chemical use towards green analytical chemistry. Indicators (phenolphthalein, thymol blue and butterfly pea flower extract as a natural indicator) sorbed on a solid support, were employed in acid-base titration, in both homogenous aqueous and heterogenous aqueous organic phases. Applications of the developed techniques to some real samples, such as vinegar, colored fruit juice and vegetable oil, have been demonstrated.

Keywords: Titration; green analytical chemistry; natural reagent; solid sorbed indicator.

MeSH terms

  • Acetic Acid / analysis
  • Adsorption
  • Anion Exchange Resins / chemistry*
  • Food Analysis / methods*
  • Fruit and Vegetable Juices / analysis
  • Green Chemistry Technology / methods*
  • Indicators and Reagents / chemistry*
  • Kaolin / chemistry*
  • Plant Oils / analysis
  • Titrimetry / methods*

Substances

  • Anion Exchange Resins
  • Indicators and Reagents
  • Plant Oils
  • Kaolin
  • Acetic Acid