Oxidation Potential Tunable Organic Molecules and Their Catalytic Application to Aerobic Dehydrogenation of Tetrahydroquinolines

Dahyeon Jung; Seol Heui Jang; Taeeun Yim; Jinho Kim

doi:10.1021/acs.orglett.8b02749

Oxidation Potential Tunable Organic Molecules and Their Catalytic Application to Aerobic Dehydrogenation of Tetrahydroquinolines

Org Lett. 2018 Oct 19;20(20):6436-6439. doi: 10.1021/acs.orglett.8b02749. Epub 2018 Oct 2.

Authors

Dahyeon Jung¹, Seol Heui Jang¹, Taeeun Yim¹, Jinho Kim¹

Affiliation

¹ Department of Chemistry and Research Institute of Basic Sciences , Incheon National University , 119 Academy-ro , Yeonsu-gu , Incheon 22012 , Republic of Korea.

PMID: 30277404
DOI: 10.1021/acs.orglett.8b02749

Abstract

In this work, oxidation potential tunable organic molecules, alkyl 2-phenyl hydrazocarboxylates, were disclosed. The exquisite tuning of their oxidation potentials facilitated a catalytic dehydrogenation of 1,2,3,4-tetrahydroquinolines in the presence of Mn(Pc) and O₂.

Publication types

Research Support, Non-U.S. Gov't