TiO₂ Polyamide Thin Film Nanocomposite Reverses Osmosis Membrane for Water Desalination

Membranes (Basel). 2018 Aug 17;8(3):66. doi: 10.3390/membranes8030066.

Abstract

In this study, TiO₂ nanoparticles were inserted into the polyamide layer of traditional thin film composite membrane. The nanoparticles were dispersed in a trimesoyl chloride-hexane solution before interfacial polymerization with m-phenylenediamine-aqueous solution. Membrane characterization was performed via contact angle measurements, atomic force microscopy (AFM), scanning electron microscopy (SEM), and water flux, salt rejection, and fouling resistance evaluation. The results indicate that TiO₂ could effectively improve membrane performance. Water flux increased from 40 to 65 L/m² h by increasing NPs concentration from 0 to 0.1 wt. %, while NaCl rejection was above 96%. Moreover, the modified membrane demonstrated better organic fouling resistance and robust antibacterial efficiency.

Keywords: interfacial polymerization (IP); nanoparticles (NPs); reverse osmosis (RO); thin film nanocomposite (TFN).