In this paper, a novel ceramic preconcentrator is manufactured using aluminum nitride (ALN) ceramics. The preconcentrator consists of a heater, a preconcentrator body, a gas inlet and a gas outlet. The adsorption material, Carbosieve SII, is loaded into the preconcentrator. The preconcentrator is integrated with a previously developed micro gas chromatographic system filled with ethylene. When operated, adequate ethylene gas is adsorbed into the preconcentrator. The application of heat pulse also successfully desorbs the ethylene gas. Tests are conducted with ethylene gas at concentrations of 10 ppm, 5 ppm and 2.5 ppm and 400 ppb, respectively. The system is also tested with ethylene gas from ripening bananas over a period of three days. No interference signal is observed in the chromatogram because of other ripening gases (e.g., carbon dioxide, oxygen, alcohol) and humidity. A detection limit of 25 ppb is realized with this system. The developed preconcentrator has several applications, e.g., in food industry and environmental monitoring.
Keywords: ceramic preconcentrator; ethylene gas; micro gas chromatographic system.