Chlorine is the most common chemical compound used for treatment of water at ppm levels, although at higher concentration it can generate harmful disinfection by-products. To easily monitor the correct level of free chlorine, cost-effective and miniaturized devices for fast and on-site detection are required. Herein, we report the development of a novel miniaturized and cost-effective screen-printed electrode modified with carbon black nanomaterial for an effective amperometric detection of free chlorine in swimming pool water. The carbon black was used as working electrode modifier for chlorine quantification at low applied potential, overcoming the fouling problem. In addition, the use of stable and cost-effective carbon black dispersion allows for a mass-production of the modified sensor by an automatable drop casting method. This sensor has demonstrated the capability to detect free chlorine in a linear range of 0.05-200 ppm with a detection limit of 0.01 ppm in standard solution as well as in swimming pool water. The achieved results demonstrated for the first time the suitability of the carbon black as electrode nanomodifier for free chlorine detection, and the possibility to produce a miniaturized and cost-effective carbon black-based printed sensor for reliable free chlorine quantification in water samples.
Keywords: Disinfectants; Electrochemical miniaturized sensors; Nanomaterials; Swimming pool water.
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