The efficiency of generic and proprietary corrosion inhibitors (based on nitrite, amine carboxylate or amino alcohol) in corrosion mitigation of carbon steel, which is exposed to concrete solutions with different amounts of chloride as well as sulfate, was studied. The corrosion protection provided by the selected corrosion inhibitors was investigated by performing a potentiodynamic polarization study. In addition, the surface morphological properties of carbon steel samples exposed to the electrolyte mixed with or without inhibitors was also evaluated by scanning electron microscopy. The potentiodynamic polarization measurements showed that the evaluated inhibitors decreased the corrosion current density by 1.6 to 6.7 times depending on the type of inhibitor and the level of sulfate concentration in the electrolyte. The performance of inhibitors based on nitrite was better than that of inhibitors based on amine carboxylate or amino alcohol. The possible mechanisms of the inhibition in the chloride plus sulfate environments are also elucidated.