Nitrogen and Sulfur Self-Doped Activated Carbon Directly Derived from Elm Flower for High-Performance Supercapacitors

Hui Chen; Feng Yu; Gang Wang; Long Chen; Bin Dai; Shanglong Peng

doi:10.1021/acsomega.8b00210

Nitrogen and Sulfur Self-Doped Activated Carbon Directly Derived from Elm Flower for High-Performance Supercapacitors

ACS Omega. 2018 Apr 30;3(4):4724-4732. doi: 10.1021/acsomega.8b00210.

Authors

Hui Chen¹, Feng Yu¹, Gang Wang¹, Long Chen¹, Bin Dai¹, Shanglong Peng²

Affiliations

¹ Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, P. R. China.
² School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, P. R. China.

Abstract

N,S-Doped activated carbon was directly prepared via a facile and cost-efficient hydrothermal reaction, followed by alkali activation of elm flower (EL)-derived biomass. The EL-derived activated carbon (ELAC) had N and S contents of 2.21 and 6.06 atom %, respectively, in addition to a high Brunauer-Emmett-Teller (BET) surface area of 2048.6 m² g^-1 and moderate pore volume of 0.88 cm³ g^-1. Owing to its high BET surface area and N/S functional groups, ELAC achieved a specific capacitance of 275 F g^-1 at a current density of 1 A g^-1 and retained a capacitance of 216 F g^-1 at 20 A g^-1. In addition, a symmetric supercapacitor based on N,S-self-doped ELAC electrode provided a capacitance of 62 F g^-1 at a current density of 10 A g^-1, with maximum energy and power densities of 16.8 Wh kg^-1 and 600 W kg^-1, respectively. The capacitance retention was also high, at 87.2%, at 4 A g^-1 after 5000 cycles.