Ultrahigh-temperature tensile creep of TiC-reinforced Mo-Si-B-based alloy

Shiho Yamamoto Kamata; Daiki Kanekon; Yuanyuan Lu; Nobuaki Sekido; Kouichi Maruyama; Gunther Eggeler; Kyosuke Yoshimi

doi:10.1038/s41598-018-28379-w

Ultrahigh-temperature tensile creep of TiC-reinforced Mo-Si-B-based alloy

Sci Rep. 2018 Jul 11;8(1):10487. doi: 10.1038/s41598-018-28379-w.

Authors

Shiho Yamamoto Kamata¹, Daiki Kanekon^{1

2}, Yuanyuan Lu¹, Nobuaki Sekido¹, Kouichi Maruyama¹, Gunther Eggeler³, Kyosuke Yoshimi⁴

Affiliations

¹ Department of Materials and Science, Graduate School of Engineering, Tohoku University, Sendai, 980-8579, Japan.
² Ferroalloys Sect. 1, Ferroalloys, Non-Ferrous & Precious Metals Dept., Metals & Coal Division, Sojitz Corporation, Tokyo, 100-8691, Japan.
³ Institute for Materials, Ruhr-University Bochum, Universitaetsstrasse 150, D-44780, Bochum, Germany.
⁴ Department of Materials and Science, Graduate School of Engineering, Tohoku University, Sendai, 980-8579, Japan. yoshimi@material.tohoku.ac.jp.

Abstract

In this study, the ultrahigh-temperature tensile creep behaviour of a TiC-reinforced Mo-Si-B-based alloy was investigated in the temperature range of 1400-1600 °C at constant true stress. The tests were performed in a stress range of 100-300 MPa for 400 h under vacuum, and creep rupture data were rationalized with Larson-Miller and Monkman-Grant plots. Interestingly, the MoSiBTiC alloy displayed excellent creep strength with relatively reasonable creep parameters in the ultrahigh-temperature range: a rupture time of ~400 h at 1400 °C under 137 MPa with a stress exponent (n) of 3 and an apparent activation energy of creep (Q_app) of 550 kJ/mol. The increasing rupture strains with decreasing stresses (up to 70%) and moderate strain-rate oscillations in the creep curves suggest that two mechanisms contribute to the creep: phase boundary sliding between the hard T₂ and (Ti,Mo)C phases and the Mo_ss phase, and dynamic recovery and recrystallization in Mo_ss, observed with orientation imaging scanning electron microscopy. The results presented here represent the first full analysis of creep for the MoSiBTiC alloy in an ultrahigh-temperature range. They indicate that the high-temperature mechanical properties of this material under vacuum are promising.