Human odor and forensics: Towards Bayesian suspect identification using GC × GC-MS characterization of hand odor

J Chromatogr B Analyt Technol Biomed Life Sci. 2018 Aug 15:1092:379-385. doi: 10.1016/j.jchromb.2018.06.018. Epub 2018 Jun 15.

Abstract

A new method for identifying people by their odor is proposed. In this approach, subjects are characterized by a GC × GC-MS chromatogram of a sample of their hand odor. The method is based on the definition of a distance between odor chromatograms and the application of Bayesian hypothesis testing. Using a calibration panel of subjects for whom several odor chromatograms are available, the densities of the distance between chromatograms of the same person, and between chromatograms of different persons are estimated. Given the distance between a reference and a query chromatogram, the Bayesian framework provides an estimate of the probability that the corresponding two odor samples come from the same person. We tested the method on a panel that is fully independent from the calibration panel, with promising results for forensic applications.

Keywords: Bayesian inference; Comprehensive two-dimensional gas chromatography; Forensics; Human hand odor; Mass spectrometry.

MeSH terms

  • Adolescent
  • Adult
  • Aged
  • Aged, 80 and over
  • Bayes Theorem
  • Child
  • Female
  • Forensic Medicine / methods*
  • Gas Chromatography-Mass Spectrometry / methods*
  • Hand / physiology*
  • Humans
  • Male
  • Middle Aged
  • Odorants / analysis*
  • Volatile Organic Compounds / analysis
  • Young Adult

Substances

  • Volatile Organic Compounds