Owing to its high specific capacity, silicon is considered as a promising anode material for lithium ion batteries (LIBs). However, the synthesis strategies for previous silicon-based anode materials with a delicate hierarchical structure are complicated or hazardous. Here, Prussian blue analogues (PBAs), widely used in ink, are deposited on the silicon nanoparticle surface (PBAs@Si-450) to modify silicon nanoparticles with transition metal atoms and a N-doped carbon layer. A facile and green synthesis procedure of PBAs@Si-450 nanocomposites was carried out in a coprecipitation process, combined with a thermal treatment process at 450 °C. As-prepared PBAs@Si-450 delivers a reversible charge capacity of 725.02 mAh g-1 at 0.42 A g-1 after 200 cycles. Moreover, this PBAs@Si-450 composite exhibits an exceptional rate performance of ∼1203 and 263 mAh g-1 at current densities of 0.42 and 14 A g-1, respectively, and fully recovered to 1136 mAh g-1 with the current density returning to 0.42 A g-1. Such a novel architecture of PBAs@Si-450 via a facile fabrication process represents a promising candidate with a high-performance silicon-based anode for LIBs.
Keywords: Prussian blue analogues (PBAs); anode; lithium ion batteries (LIBs); nanocomposite; silicon.