Emergence of Kondo Resonance in Graphene Intercalated with Cerium

Nano Lett. 2018 Jun 13;18(6):3661-3666. doi: 10.1021/acs.nanolett.8b00784. Epub 2018 May 21.

Abstract

The interaction between a magnetic impurity, such as cerium (Ce) atom, and surrounding electrons has been one of the core problems in understanding many-body interaction in solid and its relation to magnetism. Kondo effect, the formation of a new resonant ground state with quenched magnetic moment, provides a general framework to describe many-body interaction in the presence of magnetic impurity. In this Letter, a combined study of angle-resolved photoemission (ARPES) and dynamic mean-field theory (DMFT) on Ce-intercalated graphene shows that Ce-induced localized states near Fermi energy, EF, hybridized with the graphene π-band, exhibit gradual increase in spectral weight upon decreasing temperature. The observed temperature dependence follows the expectations from the Kondo picture in the weak coupling limit. Our results provide a novel insight how Kondo physics emerges in the sea of two-dimensional Dirac electrons.

Keywords: Kondo effect; angle-resolved photoemission; cerium; graphene.

Publication types

  • Research Support, Non-U.S. Gov't