Photoredox Reactions of Quinones

Chemistry. 2018 Oct 26;24(60):15955-15964. doi: 10.1002/chem.201801064. Epub 2018 Aug 7.

Abstract

Photoredox reactions of quinones are reviewed, that enable C-H bond oxidation at the vicinity of the excited quinone carbonyl and concomitant reduction of the quinone under photoirradiation. Mechanistic insights on the benzo-, naphtho-, and anthraquinones are discussed. Also the potential utilities in organic synthesis are described.

Keywords: C−H functionalization; natural products; photochemistry; quinones; redox reaction.

Publication types

  • Review