Gold Nanoparticles with Covalently Attached Polymer Chains

Angew Chem Int Ed Engl. 2001 Nov 5;40(21):4016-4018. doi: 10.1002/1521-3773(20011105)40:21<4016::AID-ANIE4016>3.0.CO;2-J.

Abstract

"Living"/controlled radical polymerization according to the atom transfer radical polymerization mechanism is a suitable method for the graft-polymerization of nanoparticles. With this method, in which the core nanoparticles remain unchanged, the chain length and therefore the thickness of the polymer shell can be adjusted.

Keywords: colloids; gold; nanostructures; organic-inorganic hybrid composites; polymers.