Novel Zinc(II) Bis(Dipyrromethenate)-Doped Ethyl Cellulose Sensors for Acetone Vapor Fluorescence Detection

J Fluoresc. 2018 Mar;28(2):477-482. doi: 10.1007/s10895-018-2220-9. Epub 2018 Apr 23.

Abstract

In this paper, we report on the results of spectrofluorimetric study of new fluorescent sensor based on [Zn2L2] doped in ethyl cellulose. The sensor optical signal is based on the rapid fluorescence quenching in the presence of acetone vapor. The acetone vapor detection limit in a gas mixture by means of sensor based on [Zn2L2] doped in ethyl cellulose is 1.68 ppb. Being highly sensitive to the acetone acetone presence, instant in response and easy to use, the sensor can find an application for the noninvasive diagnostics of diabetes as well as for the monitoring of the content of acetone acetone in the air at industrial and laboratory facilities. Graphical Abstract.

Keywords: Acetone vapor; Detection limit; Fluorescence quenching; Fluorescent sensor; Zinc(II) bis(dipyrromethenate).

MeSH terms

  • Acetone / analysis
  • Acetone / chemistry*
  • Cellulose / analogs & derivatives*
  • Cellulose / chemistry
  • Limit of Detection
  • Organometallic Compounds / chemistry*
  • Spectrometry, Fluorescence
  • Volatilization
  • Zinc / chemistry*

Substances

  • Organometallic Compounds
  • Acetone
  • ethyl cellulose
  • Cellulose
  • Zinc