Oxadiazole-Based Highly Efficient Bipolar Fluorescent Emitters for Organic Light-Emitting Diodes

Molecules. 2018 Apr 7;23(4):843. doi: 10.3390/molecules23040843.

Abstract

In this study, a series of bipolar fluorescence emitters named 2DPAc-OXD, DPAc-OXD, 2PTZ-OXD and PTZ-OXD were designed and synthesized with excellent yields. The characterization of materials was investigated by using nuclear magnetic resonance (NMR) (¹H, 13C), mass spectrometry and thermogravimetric analysis (TGA). To investigate device efficiencies, two different OLED devices (Device 1, Device 2) were fabricated with two different host materials (Bepp₂, DPEPO). The Device 2 with 2PTZ-OXD as fluorescent emitter exhibited excellent power and current efficiencies of 6.88 Lm/W and 10.10 cd/A, respectively. The external quantum efficiency of 2PTZ-OXD was around 3.99% for Device 2. The overall device properties of phenothiazine donor were better than acridine derivatives.

Keywords: acridine; bipolar; fluorescent; organic light-emitting diodes; oxadiazole; phenothiazine.

MeSH terms

  • Fluorescence
  • Luminescence
  • Magnetic Resonance Spectroscopy
  • Molecular Structure
  • Oxadiazoles / chemical synthesis*
  • Oxadiazoles / chemistry
  • Phenothiazines / chemistry*
  • Quantum Theory
  • Thermogravimetry

Substances

  • Oxadiazoles
  • Phenothiazines
  • phenothiazine