Three Zn(ii)-based MOFs for luminescence sensing of Fe3+ and Cr2O72- ions

Zhi-Zun Xiao; Li-Juan Han; Zhong-Jie Wang; He-Gen Zheng

doi:10.1039/c7dt04659f

Three Zn(ii)-based MOFs for luminescence sensing of Fe³⁺ and Cr₂O₇^2- ions

Dalton Trans. 2018 Mar 6;47(10):3298-3302. doi: 10.1039/c7dt04659f.

Authors

Zhi-Zun Xiao¹, Li-Juan Han, Zhong-Jie Wang, He-Gen Zheng

Affiliation

¹ State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, P. R. China. zhenghg@nju.edu.cn.

PMID: 29417109
DOI: 10.1039/c7dt04659f

Abstract

Three zinc metal-organic frameworks (MOFs), {ZnL(chd)}_n (1), {[Zn(L)_0.5(oba)]·DMF·H₂O}_n (2) and {[Zn(L)_0.5(sdb)]·H₂O}_n (3) [L = E,E-2,5-dihexyloxy-1,4-bis-(2-pyridin-vinyl)-benzene; H₂chd = 1,4-cyclohexanedicarboxylic acid, H₂oba = 4,4'-oxybisbenzoic acid, H₂sdb = 4,4'-sulfonyldibenzoic acid], have been hydrothermally synthesized. We explored their applications in detecting ions, and the result shows that they all show highly selective sensing for Fe³⁺ and Cr₂O₇^2- ions.