Twinning ferroelasticity facilitated by the partial flipping of phenyl rings in single crystals of 4,4'-dicarboxydiphenyl ether

R Soc Open Sci. 2018 Jan 17;5(1):171146. doi: 10.1098/rsos.171146. eCollection 2018 Jan.

Abstract

Evidence of ferroelasticity in a non-planar organic molecular crystal is presented for 4,4'-dicarboxydiphenyl ether. Ferroelasticity has been demonstrated by the micro- and macroscopic mechanical characterization of single crystals, including recording of a full hysteretic stress-strain cycle. The underlying mechanism involves the partial flipping of phenyl rings.

Keywords: ferroelasticity; organic single-crystal; twinning deformation.

Associated data

  • figshare/10.6084/m9.figshare.c.3957463