Investigation on Synthesis, Stability, and Thermal Conductivity Properties of Water-Based SnO₂/Reduced Graphene Oxide Nanofluids

Materials (Basel). 2017 Dec 27;11(1):38. doi: 10.3390/ma11010038.

Abstract

With the rapid development of industry, heat removal and management is a major concern for any technology. Heat transfer plays a critically important role in many sectors of engineering; nowadays utilizing nanofluids is one of the relatively optimized techniques to enhance heat transfer. In the present work, a facile low-temperature solvothermal method was employed to fabricate the SnO₂/reduced graphene oxide (rGO) nanocomposite. X-ray diffraction (XRD), thermogravimetric analysis (TGA), X-ray photoelectron spectroscope (XPS), Raman spectroscopy, and transmission electron microscopy (TEM) have been performed to characterize the SnO₂/rGO nanocomposite. Numerous ultrasmall SnO₂ nanoparticles with average diameters of 3-5 nm were anchored on the surface of rGO, which contain partial hydrophilic functional groups. Water-based SnO₂/rGO nanofluids were prepared with various weight concentrations by using an ultrasonic probe without adding any surfactants. The zeta potential was measured to investigate the stability of the as-prepared nanofluid which exhibited great dispersion stability after quiescence for 60 days. A thermal properties analyzer was employed to measure thermal conductivity of water-based SnO₂/rGO nanofluids, and the results showed that the enhancement of thermal conductivity could reach up to 31% at 60 °C under the mass fraction of 0.1 wt %, compared to deionized water.

Keywords: SnO2/rGO nanocomposite; dispersion stability; nanofluids; solvothermal; thermal conductivity.