Plasma-Assisted Synthesis of Monodispersed and Robust Ruthenium Ultrafine Nanocatalysts for Organosilane Oxidation and Oxygen Evolution Reactions

ChemCatChem. 2017 Nov 23;9(22):4159-4163. doi: 10.1002/cctc.201700809. Epub 2017 Oct 12.

Abstract

We report a facile and general approach for preparing ultrafine ruthenium nanocatalysts by using a plasma-assisted synthesis at <100 °C. The resulting Ru nanoparticles are monodispersed (typical size 2 nm) and remain that way upon loading onto carbon and TiO2 supports. This gives robust catalysts with excellent activities in both organosilane oxidation and the oxygen evolution reaction.

Keywords: nanostructures; oxidation; plasma chemistry; ruthenium; supported catalysts.