Critical flux investigation in treating o/w emulsion by TiO2/Al2O3-PVDF UF membrane

Water Sci Technol. 2017 Nov;76(9-10):2785-2792. doi: 10.2166/wst.2017.445.

Abstract

A standard transmembrane pressure (TMP) step method has been used in membrane fouling assessment in tube ultrafiltration (UF) membrane system treating oil water (o/w) emulsion operated at constant TMP. Three flux reduction curve with different o/w concentration based on TMP variation were concluded by experiment, then, to describe fouling behavior and identify the occurrence of fouling in the so-called critical flux. Furthermore, sub-critical and super-critical flux experiment with a long time was determined, and zero rate of flux reduction (dF/dt) was never found during the whole trial period, indicating that critical flux in o/w UF process with its strict definition could not be defined in this paper. However, quasi-critical flux exists, under which the pollution rate was very slow. Moreover, a high-efficiency four steps cleaning method: mechanic scraping, pure water wash, pure water reverse wash, and dosing cleaning, was explored. It concluded that critical flux in real o/w UF system determined by TMP-step method can be used to predict long-term critical behavior with useful data on fouling propensity.

MeSH terms

  • Aluminum Oxide / chemistry*
  • Emulsions / chemistry
  • Membranes, Artificial
  • Polyvinyls / chemistry*
  • Titanium / chemistry*
  • Ultrafiltration / instrumentation*
  • Water Purification / instrumentation

Substances

  • Emulsions
  • Membranes, Artificial
  • Polyvinyls
  • titanium dioxide
  • polyvinylidene fluoride
  • Titanium
  • Aluminum Oxide