Pristine Metal-Organic Frameworks and their Composites for Energy Storage and Conversion

Abstract

Metal-organic frameworks (MOFs), a new class of crystalline porous organic-inorganic hybrid materials, have recently attracted increasing interest in the field of energy storage and conversion. Herein, recent progress of MOFs and MOF composites for energy storage and conversion applications, including photochemical and electrochemical fuel production (hydrogen production and CO₂ reduction), water oxidation, supercapacitors, and Li-based batteries (Li-ion, Li-S, and Li-O₂ batteries), is summarized. Typical development strategies (e.g., incorporation of active components, design of smart morphologies, and judicious selection of organic linkers and metal nodes) of MOFs and MOF composites for particular energy storage and conversion applications are highlighted. A broad overview of recent progress is provided, which will hopefully promote the future development of MOFs and MOF composites for advanced energy storage and conversion applications.

Keywords: Li-based batteries; energy storage and conversion; metal-organic frameworks; photocatalysis; supercapacitors.