Experimental evaluation of main emissions during coal processing waste combustion

Abstract

The total volume of the coal processing wastes (filter cakes) produced by Russia, China, and India is as high as dozens of millions of tons per year. The concentrations of CO and CO₂ in the emissions from the combustion of filter cakes have been measured directly for the first time. They are the biggest volume of coal processing wastes. There have been many discussions about using these wastes as primary or secondary components of coal-water slurries (CWS) and coal-water slurries containing petrochemicals (CWSP). Boilers have already been operationally tested in Russia for the combustion of CWSP based on filter cakes. In this work, the concentrations of hazardous emissions have been measured at temperatures ranging from 500 to 1000°С. The produced CO and CO₂ concentrations are shown to be practically constant at high temperatures (over 900°С) for all the coal processing wastes under study. Experiments have shown the feasibility to lowering the combustion temperatures of coal processing wastes down to 750-850°С. This provides sustainable combustion and reduces the CO and CO₂ emissions 1.2-1.7 times. These relatively low temperatures ensure satisfactory environmental and energy performance of combustion. Using CWS and CWSP instead of conventional solid fuels significantly reduces NO_x and SO_x emissions but leaves CO and CO₂ emissions practically at the same level as coal powder combustion. Therefore, the environmentally friendly future (in terms of all the main atmospheric emissions: CO, CO₂, NO_x, and SO_x) of both CWS and CWSP technologies relies on low-temperature combustion.

Keywords: Coal processing wastes; Coal-water slurry containing petrochemicals; Greenhouse gases; Hazardous emissions; Maximum concentrations.