For this paper, we employ the Monte Carlo scene (MCScene) radiative transfer code to elucidate the underlying physics giving rise to the structure and colors of the antitwilight, i.e., twilight opposite the Sun. MCScene calculations successfully reproduce colors and spatial features observed in videos and still photos of the antitwilight taken under clear, aerosol-free sky conditions. Through simulations, we examine the effects of solar elevation angle, Rayleigh scattering, molecular absorption, aerosol scattering, multiple scattering, and surface reflectance on the appearance of the antitwilight. We also compare MCScene calculations with predictions made by the MODTRAN radiative transfer code for a solar elevation angle of +1°.