Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine

T I Wittmann; E I Musina; D B Krivolapov; I A Litvinov; S A Kondrashova; Sh K Latypov; A A Karasik; O G Sinyashin

doi:10.1039/c7dt03010j

Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine

Dalton Trans. 2017 Sep 26;46(37):12417-12420. doi: 10.1039/c7dt03010j.

Authors

T I Wittmann¹, E I Musina¹, D B Krivolapov¹, I A Litvinov¹, S A Kondrashova¹, Sh K Latypov¹, A A Karasik¹, O G Sinyashin¹

Affiliation

¹ A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia. elli@iopc.ru.

PMID: 28862706
DOI: 10.1039/c7dt03010j

Abstract

The first representative of the specific RSSR isomer of 14-membered tetrakisphosphine has been obtained instead of the RRRR/SSSS isomer predicted according to the empirical rule formulated recently. The geometry of the obtained 14-P₄N₂ is preorganized for the dicopper complex formation with the unique coordination mode in the row of P₄N₂ corands.