Novel Fluorometric Turn On Detection of Aluminum by Chalcone-Based Chemosensor in Aqueous Phase

J Fluoresc. 2017 Nov;27(6):2017-2022. doi: 10.1007/s10895-017-2140-0. Epub 2017 Aug 30.

Abstract

A novel, 100% water-soluble chalcone based chemosensing receptor {1-[3-(2-Hydroxy-phenyl)-3-oxo-propenyl]-naphthalen-2-yloxy}-acetic acid, L was synthesized and characterized. The receptor L is designed based on the chelation enhanced fluorescence (CHEF) mechanism. The chemosensing properties of L were evaluated by UV-vis and fluorescence spectrometric methods. It exhibits highly selective recognition ability towards aluminum ions in water over other metal ions. The binding stoichiometry of L- Al3+ complex is 2:1 by means of Job's plot and the detection limit is 5.66 × 10- 8 M.

Keywords: CHEF; Chemosensor; Detection of aluminium; Fluorometric; Novel chalcone derivative.