One-Pot Method for the Synthesis of 2,5-Unsubstituted Pyrrolidino[3',4':1,9]fullerenes

Airat R Tuktarov; Zulfiya R Shakirova; Usein M Dzhemilev

doi:10.1021/acs.orglett.7b01730

One-Pot Method for the Synthesis of 2,5-Unsubstituted Pyrrolidino[3',4':1,9]fullerenes

Org Lett. 2017 Jul 21;19(14):3863-3866. doi: 10.1021/acs.orglett.7b01730. Epub 2017 Jul 11.

Authors

Airat R Tuktarov¹, Zulfiya R Shakirova¹, Usein M Dzhemilev¹

Affiliation

¹ Institute of Petrochemistry and Catalysis, Russian Academy of Sciences . 141 Pr. Oktyabrya, Ufa 450075, Russia.

PMID: 28696120
DOI: 10.1021/acs.orglett.7b01730

Abstract

A new, efficient process has been developed for the preparation of 2,5-unsubstituted pyrrolidino[3',4':1,9]fullerenes by the Ti(O-i-Pr)₄-promoted reaction of fullerene C₆₀ with 1,3,5-perhydrotriazines generated in situ upon the reaction of primary alkyl- and benzylamines with paraformaldehyde and EtMgBr.

Publication types

Research Support, Non-U.S. Gov't