Multi-Phase Equilibrium and Solubilities of Aromatic Compounds and Inorganic Compounds in Sub- and Supercritical Water: A Review

Crit Rev Anal Chem. 2017 Nov 2;47(6):513-523. doi: 10.1080/10408347.2017.1342528. Epub 2017 Jun 30.

Abstract

Supercritical water oxidation (SCWO), as a novel and efficient technology, has been applied to wastewater treatment processes. The use of phase equilibrium data to optimize process parameters can offer a theoretical guidance for designing SCWO processes and reducing the equipment and operating costs. In this work, high-pressure phase equilibrium data for aromatic compounds+water systems and inorganic compounds+water systems are given. Moreover, thermodynamic models, equations of state (EOS) and empirical and semi-empirical approaches are summarized and evaluated. This paper also lists the existing problems of multi-phase equilibria and solubility studies on aromatic compounds and inorganic compounds in sub- and supercritical water.

Keywords: Aromatic compounds; inorganic compounds; phase equilibrium; solubility; sub- and supercritical water.

Publication types

  • Review

MeSH terms

  • Chromatography, Supercritical Fluid
  • Inorganic Chemicals / chemistry*
  • Organic Chemicals / chemistry*
  • Oxidation-Reduction
  • Thermodynamics
  • Water / chemistry*

Substances

  • Inorganic Chemicals
  • Organic Chemicals
  • Water