Organotins and new antifouling biocides in water and sediments from three Korean Special Management Sea Areas following ten years of tributyltin regulation: Contamination profiles and risk assessment

Mar Pollut Bull. 2017 Aug 15;121(1-2):302-312. doi: 10.1016/j.marpolbul.2017.06.026. Epub 2017 Jun 13.

Abstract

A simultaneous monitoring study on organotins (butyltins and phenyltins) and most frequently used alternative antifouling biocides (Irgarol 1051, Diuron, Sea-Nine 211 and M1) in water and sediments (n=44) collected from three Special Management Sea Areas operated by Korean government. The lower concentration of butyltins (BTs) than that of new antifouling biocides (NEW) was found in water but the significant greater concentration of BTs than that of NEW was still found in sediments. The tributyltin (TBT) levels in water exceeded the chronic criterion to protect seawater aquatic life at several sites. Even ten years after the ban of the use of TBT-based antifouling paint, the concentrations of TBT, Diuron and Irgarol 1051 in sediments from shipyards exceeded global sediment quality guidelines and potentially poses adverse risks on marine organisms and extremely high concentration of TBT up to 2304ng/g was found for a sediment collected at a shipyard.

Keywords: Diuron; Irgarol; Korea; Sediment; TBT; Water.

MeSH terms

  • Disinfectants / analysis*
  • Disinfectants / toxicity
  • Environmental Monitoring
  • Geologic Sediments
  • Korea
  • Risk Assessment*
  • Trialkyltin Compounds / analysis*
  • Trialkyltin Compounds / toxicity
  • Water
  • Water Pollutants, Chemical / analysis*
  • Water Pollutants, Chemical / toxicity

Substances

  • Disinfectants
  • Trialkyltin Compounds
  • Water Pollutants, Chemical
  • Water
  • tributyltin