Establishing a green platform for biodiesel synthesis via strategic utilization of biochar and dimethyl carbonate

Bioresour Technol. 2017 Oct:241:1178-1181. doi: 10.1016/j.biortech.2017.05.187. Epub 2017 Jun 1.

Abstract

To establish a green platform for biodiesel production, this study mainly investigates pseudo-catalytic (non-catalytic) transesterification of olive oil. To this end, biochar from agricultural waste (maize residue) and dimethyl carbonate (DMC) as an acyl acceptor were used for pseudo-catalytic transesterification reaction. Reaction parameters (temperature and molar ratio of DMC to olive oil) were also optimized. The biodiesel yield reached up to 95.4% under the optimal operational conditions (380°C and molar ratio of DMC to olive oil (36:1)). The new sustainable environmentally benign biodiesel production introduced in this study is greener and faster than conventional transesterification reactions.

Keywords: Biochar; Biofuels; Fatty acid methyl esters; Pseudo-catalytic transesterification.

MeSH terms

  • Biofuels*
  • Catalysis
  • Charcoal*
  • Esterification
  • Formates*

Substances

  • Biofuels
  • Formates
  • biochar
  • Charcoal
  • methyl carbonate