Rubber elastomeric nanocomposites with antimicrobial properties

Mater Sci Eng C Mater Biol Appl. 2017 Jul 1:76:269-277. doi: 10.1016/j.msec.2017.03.080. Epub 2017 Mar 11.

Abstract

In this paper we show an elastomeric nanocomposite that exhibits antibacterial and antifungal activity. It comprises a rubber blend matrix and a nanofiller, which is a modified bentonite clay (Nanobent® ZR2). We have developed innovative technology for the nanofiller incorporation into the rubber matrix. This new approach was successfully implemented in pilot production at the Polish chemical manufacturer Spoiwo (Spoldzielnia Pracy Chemiczno-Wytworczej 'Spoiwo', Radom, Poland). Here we reveal that addition of the functionalised bentonite affects the mechanical and thermal behaviour of elastomers. For example, by adding 1-3% of bentonite nanoparticles we strongly enhanced elongation and tensile stress at break, whereas stiffness remained unchanged. We observed improvement of the thermal properties of the nanocomposites yielded and extension of the temperature usage range (from -29 to 311°C). As a proof of concept we present the antimicrobial effect of elastomeric nanocomposites verified on a wide range of both pathogenic and opportunistic reference bacteria strains, as well as reference strains of yeasts. The proposed method of hydrophilic nanofiller introduction into the rubber elastomer is economically viable and enables fabrication of elastomeric elements with high added value. Their significant antibacterial and antifungal activity makes them desirable in medicine, biomedical engineering, and the food industry.

Keywords: Antibacterial; Antifungal; Bentonite; Elastomer; Nanocomposite.

MeSH terms

  • Anti-Infective Agents
  • Bentonite
  • Elastomers
  • Nanocomposites*
  • Polymers
  • Rubber

Substances

  • Anti-Infective Agents
  • Elastomers
  • Polymers
  • elastomeric polymer
  • Bentonite
  • Rubber