A simplistic approach to green future with eco-friendly luminescent carbon dots and their application to fluorescent nano-sensor 'turn-off' probe for selective sensing of copper ions

Mater Sci Eng C Mater Biol Appl. 2017 Jun 1:75:1456-1464. doi: 10.1016/j.msec.2017.03.045. Epub 2017 Mar 7.

Abstract

Zero-dimensional fluorescent nanoparticles having specificity as molecular probe appears to be strategically balanced fluorescent nano-probes. In this work, purified lemon extract and l-arginine have been thermally coupled for the extremely acute detection of Cu2+ in aqueous medium. The Cu2+ ions may be captured by the amino groups on the surface of the nano-sensor to form cupric ammine complex resulting in quenched fluorescence via an inner filter effect. Our proposed nano-probe is N-doped carbon dots (NCDs) which are efficiently selective as fluorescent chemosensor due to enormous binding affinity towards Cu2+ in a wide range of concentration (0.05-300μM) within a few minutes.

MeSH terms

  • Carbon / chemistry*
  • Cations, Divalent / analysis
  • Copper / analysis*
  • Fluorescent Dyes / chemistry*
  • Quantum Dots / chemistry*

Substances

  • Cations, Divalent
  • Fluorescent Dyes
  • Carbon
  • Copper