Solid-State Electrolyte-Gated Graphene in Optical Modulators

Adv Mater. 2017 May;29(19). doi: 10.1002/adma.201606372. Epub 2017 Mar 15.

Abstract

The gate-tunable wide-band absorption of graphene makes it suitable for light modulation from terahertz to visible light. The realization of graphene-based modulators, however, faces challenges connected with graphene's low absorption and the high electric fields necessary to change graphene's optical conductivity. Here, a solid-state supercapacitor effect with the high-k dielectric hafnium oxide is demonstrated that allows modulation from the near-infrared to shorter wavelengths close to the visible spectrum with remarkably low voltages (≈3 V). The electroabsorption modulators are based on a Fabry-Perot-resonator geometry that allows modulation depths over 30% for free-space beams.

Keywords: HfO2; Pauli blocking; double layers; field-effect transistors; graphene heterostructures.