Effects of papermaking sludge-based polymer on coagulation behavior in the disperse and reactive dyes wastewater treatment

Abstract

In this study, papermaking sludge was used as the raw biomass material to produce the lignin-based flocculant (LBF) by grafting quaternary ammonium groups and acrylamide. LBF was used as a coagulant aid with polyaluminum chloride (PAC) to treat reactive and disperse dyes wastewater. Effects of dosing method, pH, hardness and stirring speed on the coagulation behavior and floc properties were studied. Results showed that the superior coagulation efficiency and recovery factor were achieved by PAC+LBF compared with PAC and LBF+PAC. The primary mechanisms of LBF in the treatment of disperse and reactive dye solutions were charge neutralization and bridging effect, respectively. In the dual-coagulation, the impact of pH on the coagulation efficiency was weak during pH range of 5-9. Moderate hardness could enhance the floc properties due to the decrease of electrostatic repulsion and the chelation of Ca(II) and LBF. Besides, flocs coagulated by PAC+LBF had a stronger anti-crush ability.

Keywords: Dual-coagulant; Floc structure; Flocculation index; Papermaking sludge; Recovery factor.