We present a single-capture photometric stereo method using a hyperspectral camera. A spectrally and spatially designed illumination enables a point-wise estimation of reflectance spectra and surface normals from a single hyperspectral image. The illumination works as a reflectance probe in wide spectral regions where reflectance spectra are measured, and the full spectra are estimated by interpolation. It also works as the resource for shadings in other spectral regions. The accuracy of estimation is evaluated in a simulation. Also, we prepare an experimental setup and demonstrate a surface reconstruction against a real scene.