PdAuCu Nanobranch as Self-Repairing Electrocatalyst for Oxygen Reduction Reaction

Abstract

During start-up and shut-down operations of fuel cells, high potential is inevitably experienced at cathode, which leads to the deterioration of the oxygen reduction electrocatalyst. The design of catalysts that can repair themselves under severe conditions has been identified as a primary challenge for fuel cells. Herein, self-supported PdAuCu branched nanostructure is synthesized by a hydrothermal method. By smartly utilizing the high-potential treatment, the activity of PdAuCu is significantly enhanced owing to the synergistic effect between the Pd and Cu^II generated by such treatment. Moreover, the high activity of PdAuCu can be well maintained by repeating the high-potential treatment. We hence propose this catalyst as a "self-repairing" catalyst in a broad sense.

Keywords: electrocatalyst; oxygen reduction reaction; palladium; self-repair; synergistic effect.