Borinic Acid Polymer: Simplified Synthesis and Enzymatic Biofuel Cell Application

Macromol Rapid Commun. 2017 Mar;38(6). doi: 10.1002/marc.201600687. Epub 2017 Feb 7.

Abstract

A simplified one-pot and less harmful method has been introduced for the synthesis of borinic acid monomer. The corresponding borinic acid polymer (PBA) has been prepared by reversible addition-fragmentation chain transfer polymerization. Property investigations confirm the characteristics of PBA as a new type of "smart material" in the field of thermo-responsive polymer. The potential application of PBA in the field of enzymatic biofuel cell has been illustrated with a wide open circuit potential of 0.92 V.

Keywords: biofuel cell; borinic acid polymer; microporous film; thermo-responsive; upper critical solution temperature.

MeSH terms

  • Bioelectric Energy Sources*
  • Borinic Acids / chemistry*
  • Molecular Structure
  • Oxidoreductases / metabolism*
  • Particle Size
  • Polymerization*
  • Polymers / chemical synthesis*
  • Polymers / chemistry*
  • Polymers / metabolism
  • Porosity
  • Surface Properties

Substances

  • Borinic Acids
  • Polymers
  • Oxidoreductases