The syntheses of tris(organostannyl)methanes HC(SnX n Ph(3-n))3 (1, n=0; 2, n=1, X=I; 3, n=1, X =F; 4, n=1, X=Cl; 5, n=1, X=OAc; 6, n=2, X=I; 7, n=2, X=Cl) and the organostannate complexes Et4N[HC(SnIPh2)3⋅F] (8), Ph4P[HC(SnClPh2)3⋅Cl] (9), and [Ph4P]2[HC(SnCl2Ph)3⋅2 Cl] (10) are reported. The compounds were characterized by 1H, 13C, 19F, and 119Sn NMR spectroscopy, IR spectroscopy, electrospray mass spectrometry, and (with the exception of 3) single-crystal X-ray diffraction analysis. From the reaction between 2 and AgClO4 resulted the unprecedented hexanuclear organotin oxocluster [HC{Sn(ClO4)2Ph2}2Sn(OH)2Ph]2 (11), the molecular structure of which was elucidated by using X-ray crystallography.
Keywords: X-ray diffraction; anion complexation; organostannate complex; organotin oxocluster; tin.