Fluence Threshold Behaviour on Ablation and Bubble Formation in Pulsed Laser Ablation in Liquids

Chemphyschem. 2017 May 5;18(9):1084-1090. doi: 10.1002/cphc.201601198. Epub 2017 Feb 3.

Abstract

The ablation yield and bubble-formation process during nanosecond pulsed-laser ablation of silver in water are analysed by stroboscopic videography, time-resolved X-ray radiography and in situ UV/Vis spectroscopy. This process is studied as function of lens-target distance and laser fluence. Both the ablation yield and the bubble-cavitation process exhibit threshold behaviour as a function of fluence, which is linked to the efficiency of coupling of energy at the water/target interface. Although ablation happens below this threshold, quantitative material emission is linked to bubble formation. Above the threshold, both bubble size and ablation show linear behaviour.

Keywords: X-ray radiography; nanoparticles; productivity; pulsed laser ablation; silver.