Sandwich-Type Polyoxotungstate Consisting of Two Different Trilacunary Keggin-Type Units

Zhan-Gang Han; Hui-Xia Zhang; De-Shun Zhang; Chun-Na Liu; Ran Zheng; Gui-Bin Xia; Xiao-Xiao Wang

doi:10.1021/acs.inorgchem.6b01848

Sandwich-Type Polyoxotungstate Consisting of Two Different Trilacunary Keggin-Type Units

Inorg Chem. 2016 Dec 19;55(24):12488-12491. doi: 10.1021/acs.inorgchem.6b01848. Epub 2016 Nov 23.

Authors

Zhan-Gang Han¹, Hui-Xia Zhang¹, De-Shun Zhang¹, Chun-Na Liu¹, Ran Zheng¹, Gui-Bin Xia¹, Xiao-Xiao Wang¹

Affiliation

¹ College of Chemistry & Material Science, Hebei Normal University , Shijiazhuang, Hebei 050024, China.

PMID: 27989157
DOI: 10.1021/acs.inorgchem.6b01848

Abstract

A unique mixed W/Sb/Mn/Ag sandwich-type metal-O cluster was isolated, in which the six-membered {Ag₄O₃[Mn(OH₂)]₂}²⁺ cationic belt is sandwiched between two different anionic slices: the trilacunary B-β-[SbW₉O₃₃]^9- and the central-atom-lost A-α-{[Mn(OH₂)]₂W₇O₃₂}^18-.