Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry

Molecules. 2016 Nov 6;21(11):1482. doi: 10.3390/molecules21111482.

Abstract

Even if water is the natural environment for bioorganic reactions, its use in organic chemistry is often severely limited by the high insolubility of the organic derivatives. In this review, we introduce some examples of the use of water to perform organoselenium chemistry. We mainly discuss the advantages of this medium when the recyclability is demonstrated and when the water can control the selectivity of a reaction or enhance the reaction rate.

Keywords: catalysis; coupling; epoxide; michael addition; on-water reactions; oxidation; selenium; water; zinc.

Publication types

  • Review

MeSH terms

  • Catalysis
  • Chemistry, Organic / methods
  • Organoselenium Compounds / chemistry*
  • Water / chemistry*

Substances

  • Organoselenium Compounds
  • Water