Fluid-like Surface Layer and Its Flow Characteristics in Glassy Nanotubes

Nano Lett. 2016 Dec 14;16(12):7545-7550. doi: 10.1021/acs.nanolett.6b03377. Epub 2016 Nov 4.

Abstract

We show that amorphous silica and Si nanotubes can flow at room temperature under Giga-Pascal order stress when going to the nanometer scale. This creep behavior is unique for the amorphous nanotubes and is absent in crystalline Si nanotubes of similar dimensions. A core-shell model shows that there exists an approximately 1 nm thick viscoelastic "fluid-like" surface layer, which exhibits a room temperature viscosity equivalent to that of bulk glass above 1000 °C.

Keywords: Glass transition; core-shell model; creep strain; silica nanotube; silicon nanotube; viscoelasticity.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.