Gold triangular nanoprisms and nanodecahedra (pentagonal bipyramids) were synthesized in the absence and presence of nanoseeds by a simple solvothermal synthesis through the reduction of Auric Chloride (HAuCl4) with poly(vinylpyrrolidone) (PVP) in N,N-dimethylformamide (DMF), respectively. These gold nanoparticles exhibit two plasmon resonance bands. The interaction of these gold nanoparticles with luminol was investigated using UV-vis and fluorescence spectroscopy since hefty number of environmental and biological sensors are based on the combination of luminol and gold nanoparticles. The gold nanoparticles quenches the fluorescence of luminol through a static quenching mechanism, i.e., ground state complex formation, which was confirmed by both absorption spectroscopy as well as time-resolved fluorescence spectroscopy. The Stern-Volmer quenching constant and the effective quenching constant determine that gold nanodecahedra has more interaction with luminol than that of triangular gold nanoprisms. The distance between the gold nanoparticles and luminol, calculated using FRET theory, is less than 8 nm, which indicates efficient energy transfer during interaction. These results are expected to be useful for the development of novel sensors.