Preparation of SERS-active substrates based on graphene oxide/silver nanocomposites for rapid zdetection of l-Theanine

Food Chem. 2017 Feb 15:217:511-516. doi: 10.1016/j.foodchem.2016.09.010. Epub 2016 Sep 6.

Abstract

A kind of graphene oxide/silver (GO/Ag) nanocomposites with high Surface enhanced Raman scattering (SERS) activity were fabricated via a facile and green liquid phase reduction method. The synthesized materials were characterized in detail using various microscopic and spectroscopic techniques. In this method, the GO sheets worked as a holder which makes silver nanoparticles (AgNPs) aggregate to a particular morphology, and under a suitable dosage of silver ions, well-dispersed AgNPs on the surface of GO were obtained, which could generate more "hot spots" of SERS. Moreover, SERS technique based on the obtained GO/Ag nanocomposites was used as an effective way to detect l-Theanine. The detection limit was estimated to be as low as 10(-7)M, and a multivariate linear regression model for the concentration of l-Theanine was established. The optimal fitting equation is Y=5.6765+0.0307X1458-0.0267X1251.

Keywords: Graphene oxide; SERS; Silver nanoparticles; l-Theanine.

MeSH terms

  • Glutamates / analysis
  • Graphite / chemistry*
  • Metal Nanoparticles / chemistry*
  • Nanocomposites / chemistry*
  • Oxides / chemistry
  • Silver / chemistry*
  • Silver Compounds / chemistry
  • Spectrum Analysis, Raman / methods

Substances

  • Glutamates
  • Oxides
  • Silver Compounds
  • Silver
  • Graphite
  • theanine
  • disilver oxide