From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of Cd(II) using (113)Cd solid-state NMR

Jamie M Frost; Libor Kobera; Amélie Pialat; Yixin Zhang; Scott A Southern; Bulat Gabidullin; David L Bryce; Muralee Murugesu

doi:10.1039/c6cc04940k

From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of Cd(II) using (113)Cd solid-state NMR

Chem Commun (Camb). 2016 Aug 23;52(70):10680-3. doi: 10.1039/c6cc04940k.

Authors

Jamie M Frost¹, Libor Kobera¹, Amélie Pialat¹, Yixin Zhang¹, Scott A Southern¹, Bulat Gabidullin¹, David L Bryce¹, Muralee Murugesu¹

Affiliation

¹ Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, ON, Canada K1N 6N5. m.murugesu@uottawa.ca David.Bryce@uottawa.ca.

PMID: 27507123
DOI: 10.1039/c6cc04940k

Abstract

Studies of three related Cd(II) systems (a discrete [Cd(II)2] unit, a one-dimensional [Cd(II)2]n coordination polymer and a Cd(II)-based MOF) all derived from the ligand 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine, reveal an exceptionally rare example of (113)Cd-(113)Cd J coupling in the polymer that is detectable by solid-state NMR ((2)JCd-Cd = ∼65 Hz).